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OK I found the problem. It's the last FAQ on the Partition Saving site and the English is a little broken. DOS can't write new files to NTFS, therefore you have to create any blank file, a text file would be good, with the name you're going to use to save the image in Partition Saving and overwrite it. Do this in Windows before you boot from the CD. Boot from the CD, launch Partition Saving, then when you come to the save section, select the text file for the destination file and overwrite it.
DOS can overwrite existing files but not create new ones on NTFS. It gets worse, you're going to have to estimate how many files you'll need because for some reason Partition Saving can't save larger than 2GB files so the first file apparently must have the suffix PAR and the second one P01, P02 etc. A simpler option might be to make a new partition just for the destination backups and format it something other than NTFS. You still have the 2GB limit but you don't have to make corresponding text files first.
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